You have 15.0 L of nitrogen gas at 100°C and 200 kPa. What volume of gas will you have at STP
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You have 15.0 L of nitrogen gas at 100°C and 200 kPa. What volume of gas will you have at STP

[From: ] [author: ] [Date: 12-02-11] [Hit: ]
. plug and chug... and remember T must be on an absolute temperature scale (R or K........
Help with chemistry please. I've never really gotten how to do this, so don't be afraid to show your work :)

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my recommendation to all students studying these 2 state gas law problems is this..

(1) start with P1V1/(n1T1) = P2V2/(n2T2)
(2) rearrange for your desired unknown
(3) canceling anything held constant
(4) solve... plug and chug... and remember T must be on an absolute temperature scale (R or K... never °C nor °F)

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starting with
P1V1/(n1T1) = P2V2/(n2T2)

rearranging.
V2 = V1 x (P1/P2) x (T2/T1) x (n2/n1)

assuming n is constant.. n2 = n1.. and we can cancel that
V2 = V1 x (P1/P2) x (T2/T1)

solving..
V2 = 15.0L x (200kPa / 101.325 kPa) x (273.15K / 373.15K)
V2 = 21.7L

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notice how I grouped like terms? that will help you keep P1, T2, n2 in the numerator of the fractions
notice how this 1 equation can replace all those charles laws, boyles law, combined gas law etc?

why is that? because they are all special cases of P1V1/(n1T1) = P2V2/(n2T2) with different things held constant. And by canceling whatever is constant, we naturally derive those equations.

Where does P1V1/(n1T1) = P2V2/(n2T2) come from? the ideal gas law. same as the rest of those specialized gas laws.
PV = nRT
PV/(nT) = R = a universal constant
so any PV/(nT) = any other PV/(nT)
and..
'P1V1/(n1T1) = P2V2/(n2T2) = P3V3/(n3T3) = P4V4/(n4T4) etc..

your choice.. memorize all 15 variations of P1V1/(n1T1) = P2V2/(n2T2) and when they apply and hope to God you get the right equation come test time
OR
memorize P1V1/(n1T1) = P2V2/(n2T2) (or at least where it came from) and learn how to use it.

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questions?

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http://chemistry.about.com/od/homeworkhe…

http://www.shodor.org/unchem/math/units/…

http://www.chemistrysurvival.com/pdf/Che…

http://www.arbuiso.com/handouts/54gaspro…
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