Reactions at Electrodes (can anyone help me!)
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Reactions at Electrodes (can anyone help me!)

[From: ] [author: ] [Date: 12-04-09] [Hit: ]
Which half-reaction will take place at the cathode during the electrolysis of molten MgCl2?Cl2 + 2e- --> 2Cl--The thing to remember in any cell, electrolytic or galvanic/voltaic, is that oxidation always occurs at the anode.So reduction occurs at the cathode. In a reduction half-reaction,......
Which half-reaction will take place at the cathode during the electrolysis of 1.0 M H2O2 solution containing 1.0 M H2SO4?

2H2O --> O2 + 4H+ + 4e-
2H+ + 2e- --> H2
H2O2 --> O2 + 2H+ + 2e-
H2O2 + 2H+ + 2e- --> 2H2O

I thought the answer was H2 + 2OH^1 --> 2H2O + 2e^- but that isn't an option.

Which half-reaction will take place at the cathode during the electrolysis of molten MgCl2?
Mg2+ + 2e- --> Mg (I think this one is right)
Mg --> Mg2+ + 2e-
2Cl- --> Cl2 + 2e-
Cl2 + 2e- --> 2Cl-

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The thing to remember in any cell, electrolytic or galvanic/voltaic, is that oxidation always occurs at the anode.

So reduction occurs at the cathode. In a reduction half-reaction, the electrons appear on the left side. So in the first one:

H2O2 + 2H+ +2e- ===> 2H2O

In the second one:

Mg2+ + 2e- ===> Mg

The other one, Cl2 + 2e- ===> 2Cl- is not an option, because you don't start with any Cl2.
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