Which among the given acids is the strongest
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Which among the given acids is the strongest

[From: ] [author: ] [Date: 11-05-19] [Hit: ]
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a) Cl-CH2-COOH
b) Br-CH2COOH
c) O2N-CH2COOH
d) NC-CH2COOH

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2-Nitroethanoic acid is the strongest out of these. Remember that -NO2 group has the maximum -I effect ie ability to withdraw electrons towards itself thereby making the hydrogens of -COOH group strongly delta positive.
Next in the order will be 2-cyanoethanoic acid because its -I effect is lesser than -NO2
then 2-chloroethanoic acid where chlorine is an even less electron withdrawing element and finally the weakest acid is 2-bromoethanoic acid with Br exhibiting the lowest electron withdrawing tendencies out of these groups.

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( a) O2 N- CH2 -COOH NITRO -ACETIC ACID
reason----------------- due to - I- effect of NO2 [ -- ve - inductive effect of NITRO gp ]
electron withdrawing effect ( - ve I -effect )---------------------------------------… ORDER OF DECREASING -ve I effect
NO2>F>COOH>Cl>Br>I> OH > OR
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