Given 3 thermochemical eq.,calculate the standard enthalpy of formation (in kilojoules per mole) of CuO(s).
Favorites|Homepage
Subscriptions | sitemap
HOME > > Given 3 thermochemical eq.,calculate the standard enthalpy of formation (in kilojoules per mole) of CuO(s).

Given 3 thermochemical eq.,calculate the standard enthalpy of formation (in kilojoules per mole) of CuO(s).

[From: ] [author: ] [Date: 12-05-14] [Hit: ]
5 kJ mol-1]-Here we apply the Hesss Law of constant heat summation.We have to invert the 2nd equation and hence we get Hr=+297.0 kJ mol-1.2Cu + O2 = 2CuO (All the rest of the terms on either side of the equations cancel.The addition follows simple algebraic laws.Hence net enthalpy of formation of 2CuO = -79.......
Given the following thermochemical equations, calculate the standard enthalpy of formation (in kilojoules per mole) of CuO(s).

can you help me with this? i'm confused on how to do this :(

2Cu(s) + S(s) Cu2S(s) [ΔrH° = –79.5 kJ mol-1]
S(s) + O2(g) SO2(g) [ΔrH° = –297 kJ mol -1]
Cu2S(s) + 2O2(g) 2CuO(s) + SO2(g) [ΔrH° = –527.5 kJ mol-1]

-
Here we apply the Hess's Law of constant heat summation.
We also know that ;
Cu +(1/2) O2 =CuO

We have to invert the 2nd equation and hence we get Hr=+297.0 kJ mol-1.

Noe adding the above three equations we get ;
2Cu + O2 = 2CuO (All the rest of the terms on either side of the equations cancel.The addition follows simple algebraic laws.)

Hence net enthalpy of formation of 2CuO = -79.5+297-527.5= -310.0 kJ mol-1.

Now the enthalpy of formation of CuO IS -310/2=-155 kJ mol-1.

For better under standing of Hess's Law go here http://en.wikipedia.org/wiki/Hess's_law.

Hope this helped. :)
1
keywords: per,standard,eq,enthalpy,thermochemical,Given,CuO,of,mole,formation,in,kilojoules,calculate,the,Given 3 thermochemical eq.,calculate the standard enthalpy of formation (in kilojoules per mole) of CuO(s).
New
Hot
© 2008-2010 http://www.science-mathematics.com . Program by zplan cms. Theme by wukong .