Calculating pH using pKa
Favorites|Homepage
Subscriptions | sitemap
HOME > Chemistry > Calculating pH using pKa

Calculating pH using pKa

[From: ] [author: ] [Date: 11-05-31] [Hit: ]
20mL of 0.1300M ammonium chloride solution? pKa for NH4+ = 9.a) 9.b) 9.c) 8.......
Im stuck on this question, can someone explain to me how to do it?

what is the pH for the solution made from 11.10mL of 0.2780 M NaOH solution mixed with 70.20mL of 0.1300M ammonium chloride solution? pKa for NH4+ = 9.241
a) 9.53
b) 9.24
c) 8.95
d) 9.71
e) 8.77

-
Well I'm guessing this is a buffer system so you use the henderson equation:

pH = pKa + log(base/acid)

instead of the conc. of base and acid you number or moles because after they are mixed their concentrations change.

NaOH => n = CV = 11.1*.278 = 3.0858
NH4Cl => n = CV = 70.2*.13 = 9.126

(if you've noticed I didn't bother changing to L because you're going to divide them anyway so the units cancel and if you did change to L that would cancel)

pH = 9.241 + log ( 3.0858/9.216) = 8.77
1
keywords: pKa,Calculating,using,pH,Calculating pH using pKa
New
Hot
© 2008-2010 http://www.science-mathematics.com . Program by zplan cms. Theme by wukong .